The Chapelcross site ceased generating electricity in 2004 and its cooling towers came down a few years later.
It covers an area of more than 210 hectares (520 acres).
Dumfries and Galloway Council leader Gail Macgregor said the masterplan set out a “clear vision” for delivering jobs for the region.
She said they were working with the Nuclear Decommissioning Authority and South of Scotland Enterprise to make the site a “powerful force for change”.
Plans are also in development for a battery energy storage facilily on land nearby.
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