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Paolini had a breakthrough year in 2024, reaching the French Open and Wimbledon finals and was regarded a title contender in Paris.
The 29-year-old came into the tournament in good form after winning the Italian Open last month, and started well, taking the opening three games.
After the pair traded breaks, Paolini pummelled a forehand winner past Svitolina for the decisive one to take the first set 6-4.
As both struggled to hold in the second set, Paolini served at 5-3, but Svitolina saved two match points and forced a tie-break.
The 30-year-old held off another match point in the tie-break before winning the set and taking control in the deciding third set.
Svitolina dominated with her forehand, hitting 10 winners to Paolini’s four, before a backhand down the line secured her place in the last-eight.
BBC News
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